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At higher temperatures, CO 2 has poor solubility in water, which means there is less CO 2 available for the photosynthetic reactions. The enrichment of bone 13 C also implies that excreted material is depleted in 13 C relative to the diet. The carbon exchange between atmospheric CO 2 and carbonate at the ocean surface is also subject to fractionation, with 14 C in the atmosphere more likely than 12 C to dissolve in the ocean.
This increase in 14 C concentration almost exactly cancels out the decrease caused by the upwelling of water containing old, and hence 14 C depleted, carbon from the deep ocean, so that direct measurements of 14 C radiation are similar to measurements for the rest of the biosphere.
Correcting for isotopic fractionation, as is done for all radiocarbon dates to allow comparison between results from different parts of the biosphere, gives an apparent age of about years for ocean surface water. The CO 2 in the atmosphere transfers to the ocean by dissolving in the surface water as carbonate and bicarbonate ions; at the same time the carbonate ions in the water are returning to the air as CO 2.
The deepest parts of the ocean mix very slowly with the surface waters, and the mixing is uneven. The main mechanism that brings deep water to the surface is upwelling, which is more common in regions closer to the equator.